Metal-free disazo and polyazo compounds having at least one 6-hydroxypyrid-2-one coupling component radical linked to a 1-amino- or hydroxy-3-amino- or hydroxybenzene coupling component radical and metal complexes thereof

ABSTRACT

Compounds of the formula ##STR1## 1:1 and 1:2 metal complexes thereof, salts of such compounds and metal complexes and mixture thereof, wherein 
     each of B 1  and B 2  is independently hydroxy or amino, 
     each D is independently ##STR2##  wherein R is hydrogen, C 1-4  alkyl, C 5-6  cycloalkyl, phenyl, benzyl or phenylethyl, 
     R 1  is hydrogen, cyano, --COOR 4 , --CONR 5  R 6 , --SO 2  NR 5  R 6 , ##STR3##  wherein each R 3  is independently hydrogen, C 1-4  alkyl, --NR 5  R 6  or --CONR 5  R 6 , 
     R 4  is C 1-6  alkyl or phenyl(C 1-3  alkyl), 
     R 7  is C 1-4  alkyl, 
     R 8  is hydrogen or C 1-4  alkyl, and 
     R 9  is --S--, --O-- or --NR 5  --, 
     R 2  is hydrogen, hydroxy or C 1-4  alkoxy, 
     R 2a  is hydrogen, C 1-4  alkyl or halo, 
     M is hydrogen; C 1-8  alkyl; (C 1-4  alkoxy)C 1-4  alkyl; C 2-4  hydroxyalkyl; C 5-6  cycloalkyl; C 5-6  cycloalkyl substituted by 1 to 3 C 1-4  alkyls; phenyl(C 1-3  alkyl); phenyl (C 1-3  alkyl) the phenyl group of which is substituted by 1 to 3 C 1-4  alkyls; --NR 11  R 12  ; --A 1  --NR 13  R 14  ;--A 2  --N.sup.⊕ R 13  R 14  R 15  A.sup.⊖  or ##STR4##  wherein A 1  is C 1-6  alkylene or C 2-6  alkenylene, 
     A 2  is C 2-6  alkylene or C 2-6  alkenylene, 
     R 10  is C 1-10  alkylene; C 2-10  alkenylene; alkylene or alkenylene having a maximum of 10 carbon atoms and interrupted by 1 or 2 atoms selected from oxygen and nitrogen; phenylene; or cyclohexylene, 
     R 16  is hydrogen, halo, nitro, C 1-4  alkyl or C 1-4  alkoxy, 
     R 20  is hydrogen, --CO--(CH 2 ) m  --NR 11  R 12 , --CO--(CH 2 ) m  --N.sup.⊕ R 13  R 14  R 15  A.sup.⊖ or ##STR5##  wherein m is 1 to 6, with the proviso that R 20  is other than hydrogen when g is 0, and 
     q is 0 or 1, 
     v is 0, 1 or 2, and 
     each n is independently 0 or 1, 
     are basic dyes useful for dyeing and printing paper, leather and textile substrates.

This is a continuation of application Ser. No. 07/270,937, filed Nov. 14, 1988 and now abandoned, which is a continuation-in-part of application Ser. No. 07/050,182, filed May 14, 1987 and now abandoned.

The invention relates to basic compounds useful for dyeing or printing substrates such as paper, textile and leather.

According to the invention, there is provided compounds of formula I ##STR6## or salts thereof, in which each n, independently is 0 or 1,

each of B₁ and B₂, independently is --OH or --NH₂, and

each D, independently, is a radical of formula II ##STR7## in which each v, independently, is 0, 1 or 2;

each R, independently, is hydrogen, C₁₋₄ alkyl, C₅₋₆ cycloalkyl, phenyl, benzyl or phenylethyl,

each R₁, independently, is hydrogen, --CN, --COOR₄, --CONR₅ R₆, --SO₂ NR₅ R₆, ##STR8## in which each R₃, independently, is hydrogen C₁₋₄ alkyl, --NR₅ R₆ or --CONR₅ R₆ ;

each R₄, independently, is C₁₋₆ alkyl or phenyl-(C₁₋₃ alkyl);

each of R₅ and R₆, independently, is hydrogen or C₁₋₄ alkyl or, independently, R₅ and R₆ together with the N-atom to which they are attached form a saturated ring which contains one to three hetero atoms and is unsubstituted or substituted by one to three C₁₋₄ alkyl;

each R₇, independently, is C₁₋₄ alkyl;

each R₈, independently, is hydrogen or C₁₋₄ alkyl; and

each R₉, independently, is --S--, --O-- or ##STR9## each R₂, independently, is hydrogen, hydroxy or C₁₋₄ alkoxy; each R_(2a), independently, is halo, hydrogen or C₁₋₄ alkyl, and

each M, independently, is hydrogen; C₁₋₈ alkyl; (C₁₋₄ alkoxy)C₁₋₄ alkyl; C₂₋₄ hydroxyalkyl; C₅₋₆ cycloalkyl; C₅₋₆ cycloalkyl substituted by 1 to 3 C₁₋₄ alkyl groups; phenyl-(C₁₋₃ alkyl); phenyl-(C₁₋₃ alkyl) the phenyl group of which is substituted by 1 to 3 C₁₋₄ alkyl; --NR₁₁ R₁₂ ; --A₁ --NR₁₃ R₁₄ ; --A₂.sup.⊕ R₁₃ R₁₄ R₁₅ A.sup.⊖ or --R₁₀ --NH--R_(o) ;

in which each A₁, independently, is linear or branched C₁₋₆ alkylene or linear or branched C₂₋₆ alkenylene;

each A₂, independently, is linear or branched C₂₋₆ alkylene or linear or branched C₂₋₆ alkenylene;

each R₁₀, independently is linear or branched C₁₋₁₀ alkylene; linear or branched alkylene having a maximum or ten carbon atoms and interrupted by one or two hetero atoms selected from oxygen and nitrogen: linear or branched C₂₋₁₀ alkenylene; linear or branched alkenylene having a maximum of ten carbon atoms and interrupted by one or two hetero atoms selected from oxygen and nitrogen; phenylene; or cyclohexylene;

each of R₁₁ and R₁₂, independently, is hydrogen; C₁₋₆ alkyl; C₂₋₆ alkyl monosubstituted by halo, hydroxy or cyano; phenyl(C₁₋₃ alkyl); phenyl(C₁₋₃ alkyl) the phenyl group of which is substituted by 1 to 3 substituents selected from halo, C₁₋₄ alkyl and C₁₋₄ alkyloxy; C₅₋₆ cycloalkyl; C₅₋₆ cycloalkyl substituted by 1 to 3 C₁₋₄ alkyl or, independently, R₁₁ and R₁₂ together with the N-atom to which they are attached form a saturated ring which contains one to three hetero atoms and is unsubstituted or substituted by one to three C₁₋₄ alkyl;

each of R₁₃ and R₁₄, independently, have one of the significances given above for R₁₁ and R₁₂ including the heterocyclic significances;

each R₁₅, independently, is C₁₋₄ alkyl or phenyl(C₁₋₄ alkyl),

or R₁₃, R₁₄ and R₁₅ together with the N-atom to which they are attached form a pyridinium ring; a pyridinium ring substituted by 1, 2 or 3 C₁₋₄ alkyl;

each R_(o), independently, is ##STR10## in which q is 0 or 1,

R₁₆ is hydrogen, halo, nitro, C₁₋₄ alkyl or C₁₋₄ alkoxy, and

each R₂₀, independently, is hydrogen, --CO--(CH₂)_(m) --Z or ##STR11## with the proviso that R₂₀ is other than hydrogen when q is 0, in which each m, independently, is 1 to 6,

each Z, independently, is --NR₁₁ R₁₂ or --N.sup.⊕ R₁₃ R₁₄ R₁₅ A.sup.⊖ ;

each R₁₇, independently, is halo, hydroxy, C₁₋₄ alkoxy, phenyl, amino or an aliphatic, cycloaliphatic, aromatic or heterocyclic amino group the nitrogen atom of which is attached to the 1,3,5-triazine ring,

each R₁₈, independently, is an aliphatic, cycloaliphatic, aromatic or heterocyclic amino group the nitrogen atom of which is attached to the 1,3,5-triazine ring, and

each A.sup.⊖ is independently a non-chromophoric anion,

comprising

(a) metal-free compounds of formula I and salts thereof wherein, independently,

(1) at least one n is 1,

(2) at least one v is 1,

(3) at least one R₂ is hydroxy or C₁₋₄ alkoxy, or

(4) at least one R_(2a) is halo;

(b₁) 1:1 metal complexes of metallizable compounds of formula I and salts thereof;

(b₂) 1:2 metal complexes of metallizable compounds of formula I and salts thereof containing two identical or different metallizable compounds of formula I or one metallizable compound of formula I and one metallizable compound not of said formula; and

(c) mixtures of (a) and/or (b₁) and/or (b₂);

with the provisos that

(1) when the compound of formula I is free from sulpho groups, it contains at least one water solubilising protonatable basic or cationic group, and

(2) when the compound of formula I contains at least one sulpho group the total number of water-solubilising protonatable basic and cationic groups exceeds the number of sulpho groups present in the compound of formula I by at least one.

"Halo" means fluoro, chloro, bromo or iodo, preferably chloro or bromo, particularly chloro.

The term "basic group" includes protonatable primary, secondary and tertiary amino groups.

Where any symbol appears more than once in a formula, unless indicated to the contrary, its significances are independent of one another whether or not the word "independently" is indicated.

The nitrogen atom of the --NR₁₃ R₁₄ group is preferably separated from the nitrogen atom of the pyridone ring by at least two carbon atoms.

Any aliphatic amino group is preferably a mono-C₁₋₄ alkyl- or a di-(C₁₋₄ alkyl)-amino or hydrazino group. The alkyl group may be substituted by 1 to 3 groups selected from halogen, phenyl, hydroxy and C₅₋₆ cycloalkyl.

Any cycloaliphatic amino group present is preferably C₅₋₆ cycloalkylamino, the cycloalkyl group of which may be substituted by one or two C₁₋₂ alkyl groups.

Any aromatic amino group present is preferably anilino, the phenyl ring of which is unsubstituted or substituted by one to three substituents selected from C₁₋₄ alkyl, C₁₋₄ alkoxy, halogen, hydroxy and phenoxy.

Any heterocyclic amino present is preferably derived from pyridine, triazine, pyridazine, pyrimidine or pyrazine (when unsaturated) and morpholine, pyrrolidine, piperidine, piperazine or N-methyl-piperazine (when saturated).

Preferably, at least one n is 1; more preferably, just one n is 1.

Preferably, each v is 0.

Preferably, each R_(2a) is hydrogen.

R is preferably R' where R^(') is methyl, ethyl, phenyl, benzyl or cyclohexyl. More preferably R is R" where R" is methyl or phenyl, especially methyl.

R₁ is preferably R₁ ' where R₁ ' is hydrogen, cyano, --CONR₅ 'R₆ ' or ##STR12##

More preferably R₁ is R₁ ", where R₁ " is hydrogen, cyano or ##STR13##

R₂ is preferably R₂ ' where R₂ ' is hydrogen, hydroxy or methoxy. R₂ is preferably ortho to the pyridone-azo group. More preferably, each R₂ is hydrogen.

R₃ is preferably R₃ ' where R₃ ' is hydrogen, methyl, ethyl, amino or dimethylamino. More preferably R₃ is R₃ ", where R₃ " is hydrogen or methyl.

R₅ is preferably R₅ ', where R₅ ', is hydrogen, methyl or ethyl. More preferably R₅ is R₅ ", where R₅ " is hydrogen or methyl.

R₆ is preferably R₆ ', where R₆ ' has one of the significances of R₅ ', independently.

R₅ ' and R₆ ' together with the nitrogen atom to which they are attached may also form a pyrrolidinyl, morpholino, piperidino, piperazinyl or N-(C₁₋₄ alkyl)piperazinyl radical.

R₁₀ is preferably R₁₀ ', where R₁₀ ' is linear or branched C₁₋₈ alkylene or meta- or para-phenylene. More preferably R₁₀ is R₁₀ ", where R₁₀ " is 1,2-ethylene, 1,3-propylene or meta- or para-phenylene.

R₁₁ is preferably R₁₁ ', where R₁₁ ' is hydrogen, linear or branched C₁₋₆ alkyl, linear C₂₋₃ hydroxyalkyl, benzyl, 2-cyanoethyl or 2-chloroethyl. R₁₁ is preferably R₁₁ ", where R₁₁ " is hydrogen, methyl or ethyl.

R₁₂ is preferably R₁₂ ', where R₁₂ ' has one of the significances of R₁₁ ', independently. More preferably R₁₂ is R₁₂ ", where R₁₂ " has one of the significances of R₁₁ ", independently.

R₁₁ ' and R₁₂ ' together with the nitrogen atom to which they are attached may also form a pyrrolidinyl, morpholino, piperidino, piperazinyl or N-(C₁₋₄ alkyl)-piperazinyl radical.

R₁₁ " and R₁₂ " together with the nitrogen atom to which they are attached may also form a morpholino, piperazinyl or N-methyl-piperazinyl.

R₁₃ is preferably R₁₃ ', where R₁₃ ' is linear or branched C₁₋₆ alkyl, linear C₂₋₃ hydroxyalkyl, benzyl, 2-cyanoethyl or 2-chloroethyl. More preferably R₁₃ is R₁₃ ", where R₁₃ " is methyl or ethyl.

R₁₄ is preferably R₁₄ ', where R₁₄ ' has one of the significances of R₁₃ ', independently. More preferably R₁₄ is R₁₄ ", where R₁₄ " has one of the significances of R₁₃ ", independently.

R₁₅ is preferably R₁₅ ', where R₁₅ ' is methyl, ethyl, propyl or benzyl. More preferably, R₁₅ is R₁₅ ", where R₁₅ " is methyl, ethyl or benzyl.

R₁₃ ', R₁₄ ' and R₁₅ ' together with the nitrogen atom to which they are attached may also form a pyridinium ring unsubstituted or substituted by one or two methyl groups or a radical β ##STR14## in which W is a direct bond, --CH₂ --, --O--, --S--, --SO₂ --, --SO--, --NH--, >.sup.⊕ N(R₁₅ ')₂ A.sup.⊖ or >N--R₅₀ in which R₅₀ is benzyl, C₁₋₄ alkyl or C₁₋₄ alkyl substituted by amino.

R₁₃ ", R₁₄ " and R₁₅ " together with the nitrogen atom to which they are attached may also form a pyridinium, 2- or 3-picolinium, N-methyl-morpholinium, N-methylpiperidinium, N-methyl-piperazinium or N,N'-dimethyl-piperazinium ring.

M is preferably M', where M' is hydrogen, methyl, ethyl, 2-hydroxyethyl, 2-methoxyethyl, 2-ethoxyethyl, cyclohexyl, benzyl, --CH₂ --NR₁₃ 'R₁₄ ', --(CH₂)₂ --NR₁₃ 'R₁₄ ', --(CH₂)₃ --NR₁₃ 'R₁₄ ', --(CH₂)₂ N.sup.⊕ R₁₃ 'R₁₄ 'R₁₅ ' A.sup.⊖, --(CH₂)₃ --.sup.⊕ NR₁₃ 'R₁₄ 'R₁₅ ' A.sup.⊖ or --R₁₀ '--NH--R_(o) '. Preferably M is M" where M" is methyl, ethyl, benzyl, --(CH₂)₂ --NR₁₃ "R₁₄ ", --(CH₂)₃ --NR₁₃ "R₁₄ ", --(CH₂)₂ .sup.⊕ NR₁₃ "R₁₄ R₁₅ " A.sup.⊖, --(CH₂)₃ --N.sup.⊕ R₁₃ "R₁₄ "R₁₅ " A.sup.⊖ or -- R₁₀ "--NH--R_(o) ".

R_(o) is preferably R_(o) ', where R_(o) ' is a radical ##STR15##

More preferably R_(o) is R_(o) ", where R_(o) " is a radical ##STR16##

R₁₆ is preferably R₁₆ ', where R₁₆ ' is hydrogen, chloro, nitro, methyl or methoxy. More preferably R₁₆ is R₁₆ " where R₁₆ " is hydrogen, chloro or methyl.

R₂₀ is preferably R₂₀ ', where R₂₀ ' is hydrogen, ##STR17## --CO--CH₂ --Z₁ or --CO--CH₂ --CH₂ --Z₁, in which each Z₁, independently, is --NR₁₁ 'R₁₂ ' or --.sup.⊕ NR₁₃ 'R₁₄ 'R₁₅ ' A.sup.⊖.

More preferably R₂₀ is R₂₀ ", where R₂₀ " is hydrogen, ##STR18## or --CO--CH₂ --Z₂, in which Z₂ is --NR₁₁ "R₁₂ " or --.sup.⊕ NR₁₃ "R₁₄ "R₁₅ " A.sup.⊖.

R₁₇ is preferably R₁₇ ', where R₁₇ ' is chloro, hydroxy, amino, methoxy, bis[hydroxy-C₂₋₄ alkyl]-amino, ##STR19##

in which R₁₉ is C₁₋₁₂ alkyl; C₁₋₁₂ alkyl substituted by hydroxy; alkyl having a maximum of 12 carbon atoms which is interrupted by 1 to 3 radicals selected from --NR₅ '-- and ##STR20## alkyl having a maximum of 12 carbon atoms which is substituted by hydroxy and interrupted by 1 to 3 radicals selected from --NR₅ '-- and ##STR21## in which

R₂₁ is halo, hydroxy, nitro, C₁₋₄ alkyl, C₁₋₄ alkoxy or hydrogen, and

Z_(o) is --N(CH₃)₂, --N(C₂ H₅)₂, --.sup.⊕ N(CH₃)₃ A.sup.⊖, --.sup.⊕ N(C₂ H₅)₃ A.sup.⊖, --CO--Y_(o) --Z₁, --NHCO--Y_(o) --Z₁, --CONH--Y_(o) --Z₁, --SO₂ --NH--Y_(o) --Z₁, --Y_(o) --Z₁ or --NHNHCO--CH₂ --Z₁ and

each Y independently, is linear or branched C₁₋₈ alkylene or linear or branched C₃₋₈ alkenylene,

each Y₂ independently, is linear C₁₋₆ alkylene, and

each Y_(o) independently, is linear or branched C₁₋₄ alkylene, and

R₅₁ is hydrogen, C₁₋₄ alkyl or C₁₋₄ alkyl substituted by amino.

More preferably R₁₇ is R₁₇ ", where R₁₇ " is chloro, hydroxy, amino, methoxy, mono-C₁₋₂ alkylamino, mono-hydroxy-C₂₋₄ alkylamino, bis[hydroxy-C₂₋₄ alkyl]-amino, ##STR22## in which each R₇ ', independently, is methyl or ethyl, and R₁₉ ' is --(CH₂)_(a) --NR₅ "--CH₃, --(CH₂)_(a) --NR₅ "--(CH₂)_(a) --NR₅ "C₂ H₅, --(CH₂)_(a) N.sup.⊕ (R₁₃ ")₂ --(CH₂)_(a) --N.sup.⊕ (R₁₃ ")₂ --C₂ H₅ 2A.sup.⊖, --(CH₂)_(a) --NR₅ "--C₂ H₅, --(CH₂)_(a) --.sup.⊕ N(R₁₃ ")₂ C₂ H₅ A.sup.⊖, --NHCO--CH₂ --Z₂, --CH₂ --CO--NH--Y'--Z₂, --Y'--Z₂ ', ##STR23## in which each Z_(o) ' independently, is --N(CH₃)₂ ; --.sup.⊕ N(CH₃)₃ A.sup.⊖ ; --CONH--Y_(o) '--Z₂ ; --NHCO--Y_(o) '--Z₂ ; --CO--Y_(o) '--Z₂ ; --SO₂ NH--Y_(o) '--Z₂ ; --Y_(o) '--Z₂ or --NHNH--COCH₂ --Z₂ ;

each Y', independently, is linear or branched C₁₋₄ alkylene;

each Y_(o) ', independently, is linear or branched C₂₋₄ alkylene, and

a is 2 or 3.

R₁₈ is preferably R₁₈ ', where R₁₈ ' is --NR₅ 'R₁₉ in which R₅ ' and R₁₉ are as defined above. More preferably R₁₈ is R₁₈ ", where R₁₈ " is --NR₅ "R₁₉ ' in which R₅ " and R₁₉ ' are as defined above.

D is preferably D', where D' is a radical of formula IIa ##STR24##

More preferably D is D" where D" is a radical of formula IIb ##STR25##

In formulae IIa and IIb, v is preferably 0.

Preferred compounds of formula I are those in free form or salt form and in metal-free, 1:1 or 1:2 metal complex form, of formula Ia ##STR26## in which B₁, B₂, D' and n are as defined above, with the provisos (1) and (2) as indicated above.

In the compounds of formula Ia, the symbols D' are preferably distinct from each other. More preferably, at least one n is 1 and each v is 0. Most preferably, just one n is 1, and, when the compounds are in metal-free form, each R₂ ' is hydrogen.

More preferred compounds of formula I are those, in free form or salt form and in metal-free, 1:1 or 1:2 metal complex form, of formula Ib ##STR27## in which B₁, B₂, D" and n are as defined above, with the provisos (1) and (2) as indicated above.

In the compounds of formula Ib, the symbols D" are preferably distinct from each other. More preferably, n is 1, and each v is 0. Most preferably, when the compounds are in metal-free form, each R₂ ' is hydrogen.

Interesting compounds of formula I in 1:1 metal complex form and in free form or salt form are of formula III ##STR28## in which B₁, B₂ and n are as defined above and each D₁, independently, is a radical of formula IIc ##STR29## in which R, R₁, M and v are as defined above, the azo group ○ is fixed in the position 3, 4 or 5 and Me is copper, chromium, cobalt, nickel or manganese.

Preferred compounds of formula I in 1:1 metal complex form and in free form or salt form are of formula IIIa ##STR30## in which B₂, R, R₁, R₂, M, Me and v are as defined above, p is 0, 1 or 2, B₁₀ is --O-- or --NH--, the azo group ○ and the --O--Me--B₁₀ radical being in the position ortho to each other on ring C and the radical --O--Me--Be₁₀ being located on ring C in the position 3 or 4.

Further preferred compounds of formula I in 1:1 metal complex form and in free form or salt form are those of formula IIIb ##STR31## in which B₂, B₁₀, R, R₁, M, Me and v are as defined above, the azo group ○ and the --O--Me--Be₁₀ being in the position ortho to each other on the ring C and the radical --O--Me--B₁₀ being located on ring C in position 3 or 4.

When the compounds of formula I are in the form of a 1:2 metal complex, the metal Me is chromium, cobalt or iron and bound as indicated in the formulae III, IIIa and IIIb but together with a second identical or different molecule of dyestuff of formula I or with another metallisable organic compound. The negative charge of the complexed metal ion of each 1:2 complex is balanced by hydrogen or a preferably monovalent, non-chromophoric cation, for example, lithium, sodium, potassium or ammonium.

The term "salt form" includes acid addition salts (wherein, for example, one or more basic non-cationic groups are in the form of acid addition salts with, for example, a non-chromophoric acid HA, HA being an acid corresponding to A.sup.⊖, as defined and exemplified herein), salts wherein one or more acidic (e.g., sulpho) groups are in salt form (with, for example, a non-chromophoric cation such as lithium, sodium, potassium or ammonium) and internal salts (wherein, for example, the negative charge of at least one sulpho group is balanced by a cationic group of the molecule (as in Examples 72 to 137 for example).

In the compounds of formula I the anions A.sup.⊖ can be any non-chromophoric anions such as those conventional in basic dyestuff chemistry. Suitable anions include chloride, bromide, sulphate, bisulphate, methylsulphate, aminosulphonate, perchlorate, benzenesulphonate, oxalate, maleate, acetate, propionate, lactate, succinate, tartrate, malate, methanesulphonate and benzoate as well as complex anions, for example zinc chloride double salts and anions of boric acid, citric acid, glycollic acid, diglycollic acid and adipic acid or addition products of ortho boric acids with polyalcohols with at least one cis diol group present. These anions can be exchanged for each other by ion exchange resins on reaction with acids or salts (for example via the hydroxide or bicarbonate) or according to German Offenlegungsschrift 2,001,748 or 2,002,816.

Further, according to the invention there is provided a process for preparing a compound of formula I comprising reacting 1 to 3 moles of a diazotised compound of formula IV ##STR32## in which R, R₁, R₂, R_(2a), M and v are as defined above, with 1 mole of a compound of formula V ##STR33## in which B₁ and B₂ are as defined above and B₃ is hydrogen or --CH₂ OH, and, if required, the resulting compounds of formula I may be converted into the corresponding 1:1 or 1:2 metal complex form and/or into the corresponding salt form.

Compounds of formulae IV and V are known or may be made by known methods from known compounds.

Coupling to form compounds of formula I can be carried out according to known methods. Advantageously, coupling is carried out in aqueous (acid, neutral or alkali) medium at a temperature from -10° C. to room temperature, if necessary, in the presence of a coupling accelerator such as pyridine or urea. Alternatively, coupling may be effected in a mixture of solvents, for example, water and an organic solvent. When B₃ is --CH₂ OH, this group is removed in the coupling reaction. The most preferred coupling positions are the 4- and 6-positions of the compound of formula V followed by the 2-position. The compounds of formula I are usually obtained as a mixture of position isomers and used as such. However, if desired, the obtained mixtures may be separated by known methods to obtain single compounds.

Metallisation of the compounds of formula I can be achieved by known methods.

The compounds of formula I in 1:1 metal complex form may be prepared by metallising compounds of formula I in metal-free form with a metal selected from copper, cobalt, nickel, manganese and chromium.

A compound of formula I in 1:2 metal complex form may be prepared by reacting a compound of formula I or other than of formula I in metal-free form with a 1:1 metal complex of formula I when the metal is chromium, cobalt or iron.

The metallisation process to form a 1:1 metal complex of the type of formula IIIa, IIIb or III is advantageously carried out by treating 1 mole of a compound with a metallising agent containing 1, respectively 2, respectively 3 equivalents of metal.

1:1 Metal complex formation using copper can be carried out by directly reacting a compound of formula I with metal salt or by oxidative coppering preferably at 40°-70° C. and at a pH of 4-7 in the presence of a Cu(II) salt or with copper filings in the presence of H₂ O₂ or any other oxidizing agent; or demethylating coppering can be applied in a pH range of 3-4 at a high temperature.

Metallisation is carried out advantageously in aqueous medium or in a mixture of water and a water-miscible organic solvent, for example acetone, lower alkyl alcohols, dimethylformamide, formamide, glycols or acetic acid at a pH range from 1.0 to 8.0, preferably pH 2 to 7. The metallisation process may be carried out at a temperature from room temperature to the boiling point of the reaction medium.

Alternatively, metallisation may be effected in a wholly organic medium (for example dimethylformamide). Advantageously, for instance, cobaltisation may be carried out in the presence of an inorganic nitrite such as lithium, sodium, ammonium or potassium nitrite in the ratio of 2 to 6 moles of nitrite per atom gram of cobalt.

Suitable cobalt-yielding compounds are, for example, cobalt(II) and Co(III) sulphate, acetate, formate and chloride.

Copper-yielding compounds are, for example, cupric sulphate, cupric formate, cupric acetate and cupric chloride.

The nickel-yielding compounds are Ni(II) and Ni(III) compounds, such as nickel formate, nickel acetate and nickel sulphate.

Preferred manganese-yielding compounds are Mn(II) compounds and iron-yielding compounds are Fe(II) and Fe(III) compounds. Examples of these are manganese and iron formate, acetate and sulphate.

Preferred chromium-yielding compounds are Cr(II) and Cr(III) formate, acetate and sulphate.

The compounds of formula I are suitable for dyeing, padding or printing fibres, threads or textile materials, particularly natural or regenerated cellulose materials, for example cotton, polyester or synthetic polyamides modified by anionic groups.

The textile material is dyed, printed or pad-dyed in accordance with known methods. Acid modified-polyamide is dyed particularly advantageously in an aqueous, neutral or acid medium, at temperatures of 60° C. to boiling point or at temperatures above 100° C. under pressure.

The textile may also be dyed by the compounds of formula I in organic solvents.

Cellulose material is mainly dyed by the exhaust process, i.e. from a long or short bath, at room temperature to boiling temperature, optionally under pressure, whereby the ratio of the bath is from 1:1 to 1:100 and preferably from 1:20 to 1:50. If dyeing is effected from a short bath, then the liquor ratio is 1:1 to 1:15. The pH of the dyebath varies between 3 and 10 (for short and long dyebaths).

Printing may be effected in accordance with known methods.

The dyestuffs of formula I are particularly suitable for dyeing or printing paper, e.g. for the production of bulk-dyed, sized and unsized paper. The dyestuffs may similarly be used for dyeing paper by the dipping process. The dyeing of paper is effected by known methods. The compounds of formula I are especially suitable for dyeing ligneous paper, particularly wood pulp.

The compounds of formula I may also be applied to bast fibres such as hemp, flax, sisal, jute, coir or straw.

The dyestuffs of formula I are also suitable for dyeing or printing leather by known methods and dyeings with good fastness properties are obtained.

Dyeings prepared with dyestuffs of formula I on paper produce a substantially clear waste liquor which is important for environmental reasons. The dyestuffs of formula I have good build-up properties, do not bleed once applied to paper and are not pH sensitive. They have a high affinity for paper and do not mottle on ligneous paper. Dyeings produced with dyestuffs of formula I have good light fastness and the nuance on exposure for a long time to light fades in tone. The dyestuffs of formula I have good wet-fastness properties not only for water but also for alcohol, milk, soap, water, urine, sodium chloride solution, fruit juice and sweetened mineral water.

Further, the dyestuffs of formula I have good nuance stability.

For their use the compounds of formula I are suitably worked up into stable solid or liquid preparations according to known methods, advantageously by grinding or granulating or by dissolving in suitable solvents, optionally adding an assistant, e.g. a stabiliser, a solubilising or a diluting agent such as urea. Such preparations may be obtained, for example, as described in French Patent Specification Nos. 1,572,030 and 1,581,900 or in accordance with German DOS 2,001,748 and 2,001,816.

Liquid dyeing compositions are preferably as follows:

1 part by weight of a compound of formula I (in salt form)

0.01-1 part by weight of an inorganic salt (preferably 0.1 part);

0.01-1 part by weight of an organic acid such as formic, acetic, lactic, citric, propionic or methoxy acetic acid;

1-8 parts by weight of water; and

0-5 parts by weight of a solubilising agent such as a glycol (diethylene glycol, triethylene glycol or hexylene glycol), a glycol ether such as methyl cellosolve, methylcarbitol, butylpolyglycol, urea, formamide and dimethylformamide.

Solid dyeing preparations are preferably as follows:

1 part by weight of a compound of formula I (in salt form)

0.01-1 part by weight of an inorganic salt (preferably 0.01 to 0.1 parts)

0-8 parts by weight of a diluting agent such as urea, dextrin, glucose or d-glucose).

The solid compositions may usually contain up to 10% water.

The invention will now be illustrated by the following Examples, in which all parts and percentages are by weight and all temperatures are in °C.

Each A.sup.⊖ of the compounds of Tables 1-5 may be any non-chromophoric anion, is preferably one of the non-chromophoric anions listed above and is most preferably chloride.

The dyes of the examples are mixtures that may be separated by conventional means to obtain single compounds. However, they are usually used as obtained, i.e., as mixtures.

EXAMPLE 1

22.9 Parts (0.05 M) of the compound of formula (1a) ##STR34## are diazotised according to known methods with 3.45 parts (0.05 M) of sodium nitrite at 0°-5° in the presence of 30% hydrochloric acid and then coupled with 5.5 parts (0.05 M) of 1,3-dihydroxybenzene at pH 8.0-8.5. A brown suspension is obtained containing the dyestuff of formula (1b) ##STR35## The product is a mixture of two isomers. The following metal complexes of dyestuff of formula (1b) are then prepared

(1c) 5.8 Parts (0.01 M) of the dyestuff of formula (1b) are metallized according to known methods in water at 70°, at a pH of 4.0-4.8, with 2.5 parts (0.01 M) copper sulphate (CuSO₄ ·5H₂ O). The corresponding 1:1 copper complex is obtained.

(1d) 5.8 Parts (0.01 M) of the dyestuff of formula (1b) are converted according to known methods into the corresponding 1:2 chromium complex by reaction in water at 95° with 2.5 parts (0.005 M) of chromium potassium alum (KCr(SO₄)₂ ·12H₂ O)

(1e) By following the procedure of (1d) but replacing the chromium potassium alum by 0.8 parts (0.005 M) cobalt sulphate, there is obtained the corresponding 1:2 cobalt complex.

(1f) By following the procedure of (1d) but replacing the chromium potassium alum by 1.4 parts (0.005 M) ferric chloride (FeCl₃ ·6H₂ O), there is obtained the corresponding 1:2 iron complex.

The starting compound of formula (1a) may be prepared according to known methods comprising the following steps

acetylation of 1-amino-2-hydroxy-5-nitrobenzene

reduction according to Bechamp to 1-acetylamino-2-hydroxy-5-aminobenzene

diazotation and coupling with 3-pyridinium-4-methyl-6-hydroxy-1-(3'-diemthylaminopropyl)pyrid-2-one chloride, and

hydrolysis of the acetyl group under acidic conditions.

EXAMPLE 2

22.1 Parts (0.05 M) of the compound of formula (2c) ##STR36## are diazotised according to known methods with 3.45 parts (0.05 M) of sodium nitrite at 0°-5° in the presence of 30% hydrochloric acid and then coupled with 5.5 parts (0.05 M) of 1,3-dihydroxybenzene at pH 8-9. The resulting dyestuff is of formula (2d) ##STR37##

22.1 Parts (0.05 M) of the compound of formula (2c) are diazotised and then coupled with 0.05 M of the dyestuff of formula (2d), to give a mixture of isomers of formula (2e) ##STR38## the coupling positions being indicated by an arrow.

The resulting isomer mixture of formula (2e) dyes wood pulp paper in a brown orange shade.

By following the procedure described in Example 1 or 2, the dyestuffs of formula ##STR39## in which D₁ is a radical ##STR40##

and B₁, B₂, D₂, R₁, R₂, R_(t) and M are indicated in Table 1 below, may be obtained.

                                      TABLE 1     __________________________________________________________________________                               R.sub.t                                     Position of                               (position on                                     the azo  ○1     Ex.        R.sub.1  M          R.sub.2                               ring B)                                     on ring B                                            B.sub.1                                               B.sub.2                                                  D.sub.2     __________________________________________________________________________      3         ##STR41##                 (CH.sub.2).sub.3N(CH.sub.3).sub.2                            H  H     4      OH OH H      4 "        "          H  H     4      OH OH D.sub.1      5 "        "          H  H     4      NH.sub.2                                               NH.sub.2                                                  H      6 "        "          H  H     4      NH.sub.2                                               NH.sub.2                                                  D.sub.1      7 "        "          H  H     4      NH.sub.2                                               OH H      8 "        H          H  H     3      OH OH H      9 "        H          H  H     3      OH OH D.sub.1     10 "        H          H  H     3      NH.sub.2                                               NH.sub. 2                                                  H     11 "        H          H  H     3      NH.sub.2                                               D.sub.1     12 "        H          H  H     3      OH NH.sub.2                                                  H     13 "        H          H  H     4      OH OH H     14 "        H          H  H     4      OH OH D.sub.1     15 "        H          H  H     4      OH NH.sub.2                                                  H     16         ##STR42##                 H          H  H     3      OH OH H     17 "        H          H  H     3      OH OH D.sub.1     18 "        H          H  H     4      NH.sub.2                                               NH.sub.2                                                  H     19 "        H          H  H     4      NH.sub.2                                               NH.sub.2                                                  D.sub.1     20 "        H          H  H     4      NH.sub.2                                               OH H     21         ##STR43##                 (CH.sub.2).sub.3N(C.sub.2 H.sub.5).sub.2                            H  H     3      OH OH H     22 "        "          H  H     3      OH OH D.sub.1     23 "        "          H  H     4      NH.sub.2                                               NH.sub.2                                                  H     24 "        "          H  H     4      NH.sub.2                                               OH H     25 "        "          H  H     4      OH OH H     26 CN       "          H  H     3      OH OH H     27 "        "          H  H     3      OH OH D.sub.1     28 "        "          H  H     4      OH OH H     29 "        "          H  H     4      OH NH.sub.2                                                  H     30 "        "          H  H     4      NH.sub.2                                               NH.sub.2                                                  H     31 CONH.sub.2                 "          H  H     3      OH OH H     32 "        "          H  H     3      OH OH D.sub.1     33 "        "          H  H     4      NH.sub.2                                               NH.sub.2                                                  H     34 H        "          H  H     3      OH OH H     35 H        "          H  H     3      OH OH D.sub.1     36 H        "          H  H     4      NH.sub.2                                               NH.sub.2                                                  H     37 H        "          H  H     4      NH.sub.2                                               OH H     38 CN       (CH.sub.2).sub.3 N(C.sub.2 H.sub.5).sub.2                            H  H     3      OH OH H     39 CONH.sub.2                 "          H  H     4      OH OH H     40 H        "          H  H     4      NH.sub.2                                               NH.sub.2                                                  H     41         ##STR44##                 (CH.sub.2).sub.3N(CH.sub.3).sub.2                            OH H     5      OH OH H     42 "        H          OH H     5      OH OH H     43 "        H          H  OH-(4)                                     3      OH OH H     44 H        (CH.sub.2).sub.3N(CH.sub.3).sub.2                            OH H     5      OH OH H     45 H        "          H  OH-(4)                                     3      OH OH H     46 H        "          H  H     4      OH OH H     __________________________________________________________________________

By following the procedure described in Example 1 or 2, the dyestuffs of the formula ##STR45## in which R₁, M and Me are indicated in Table 2 below, may be produced. When the compounds are in the form of a 1:2 metal complex, the metal is bound to a second molecule identical to the first one.

                  TABLE 2     ______________________________________                                      Me     Ex.  R.sub.1      M              Metal complex     ______________________________________     47           ##STR46##   (CH.sub.2).sub.3N(CH.sub.3).sub.2                                      1:1-Cu     48   "            "              1:2-Cr     49   "            "              1:2-Co     50   "            "              1:2-Fe     51   "            H              1:1-Cu     52   "            H              1:2-Cr     53   "            H              1:2-Co     54   "            H              1:2-Fe     55           ##STR47##   H              1:1-Cu     56   "            H              1:2-Fe     57   H            (CH.sub.2).sub.3 N(CH.sub.3).sub.2                                      1:1-Cu     58   H            "              1:2-Cr     59   H            "              1:2-Co     60   H            "              1:2-Fe     ______________________________________

By following the procedure described in Example 1 or 2, the dyestuffs of the formula ##STR48## in which R₁, M and Me are indicated in Table 3 below, may be produced. When the compounds are in the form of a 1:2 metal complex, the metal is bound to a second molecule identical to the first one.

                  TABLE 3     ______________________________________                                     Me     Ex.  R.sub.1       M            Metal complex     ______________________________________     61           ##STR49##    H            1:1-Cu     62   "             H            1:2-Cr     63   "             H            1:2-Co     64   "             H            1:2-Fe     65           ##STR50##    H            1:1-Cu     66   "             H            1:2-Fe     67   H             (CH.sub.2).sub.3 N(CH.sub.3).sub.2                                     1:1-Cu     68   H             "            1:2-Cr     69   H             "            1:2-Co     70   H             "            1:2-Fe     ______________________________________

EXAMPLE 71

A mixture comprising 7.7 parts (0.05 mole) of 4-aminoacetanilide and 22.9 parts (0.15 mole) of 3-aminoacetanilide is diazotised according to known methods with sodium nitrite. To the resulting diazonium salts there is added 58.5 parts (0.18 mole) of 6-hydroxy-4-methyl-1-(3'-dimethylaminopropyl)-3-pyridiniumpyrid-2-one chloride and coupling is carried out according to known methods at pH 1.8-2.2.

The acetyl groups are then removed by hydrolysis with 57.5 parts of 30% hydrochloric acid according to known methods. The resulting amino compounds are diazotised according to known methods with 13.8 parts (0.2 mole) of sodium nitrite and the corresponding diazonium salts are added dropwise to an alkaline solution of 11 parts (0.1 mole) of 1,3-dihydroxybenzene.

There is obtained a brown solution containing the dyestuff of the formula ##STR51## which dyes wood pulp paper a brown shade. It is most preferred to use this dye solution for dyeing without isolating the dye in solid form. The resulting dyestuff is a mixture of tetrakisazo dyes where in about 75% of the total number of diazo component radicals have a meta-phenylene radical and about 25% have a para-phenylene radical.

EXAMPLE 72

22.1 Parts (0.05 mole) of the compound of the formula ##STR52## are diazotised according to known methods with 3.45 parts (0.05 M) of sodium nitrite at 0°-5° in the presence of hydrochloric acid and the resulting diazonium salt is then coupled with 5.4 parts (0.05 M) of 1,3-diaminobenzene at pH 1-3. The following dyestuff of formula (72 a) ##STR53## is obtained.

26.1 Parts (0.05 M) of the diazonium salt of the compound of formula (72 b) ##STR54## prepared by diazotation of 1-amino-3acetylaminobenzene-6-sulphonic acid, coupling with the pyridone and hydrolyzing according to known methods, are coupled with 0.05 M of the compound of formula (72 a). The following mixture of isomers is obtained ##STR55## the arrows indicating the various coupling positions.

By following the procedure of Example 72, the compounds of formula (72 c) ##STR56## in which D₃ is hydrogen or a radical of formula ##STR57## and B₁, B₂, R_(a), R_(b), R₆, R₇, R₈, R₉, M_(a) and M_(b) have the significances indicated in Table 4 thereafter, may be prepared.

    __________________________________________________________________________     Significances of Ma and Mb      M.sub.1         is           H              M.sub.6                            is                              ##STR58##     M.sub.2        is          (CH.sub.2).sub.3 N(CH.sub.3).sub.2     M.sub.3        is          (CH.sub.2).sub.2 N(C.sub.2 H.sub.5).sub.2      M.sub.4         is           ##STR59##      M.sub.7                            is                              ##STR60##      M.sub.5         is           ##STR61##                          M.sub.8                            is                              ##STR62##     M.sub.10        is          (CH.sub.2).sub.2 NH.sub.2                          M.sub.9                            is                              ##STR63##     Significances of Ra and Rb     R.sub.1        is          H              R.sub.4                           is                             CN      R.sub.2         is           ##STR64##      R.sub.5                            is                              ##STR65##      R.sub.3         is           ##STR66##     __________________________________________________________________________

                                      TABLE 4     __________________________________________________________________________                     Position of                           H             Position of                     the azo  ○1                           or            the azo  ○2     Ex.        Ra          Ma R.sub.6                 R.sub.8                     on ring B                           D.sub.3                             R.sub.b                               M.sub.b                                 R.sub.7                                     R.sub.9                                         on ring C                                               B.sub.1                                                  B.sub.2     __________________________________________________________________________     73 R.sub.2          M.sub.2             SO.sub.3 H                 H   3     H --                               --                                 --  H   --    OH OH     74 R.sub.2          M.sub.2             "   H   4     H --                               --                                 --  H   --    OH NH.sub.2     75 R.sub.2          M.sub.2             "   H   4     H --                               --                                 --  H   --    NH.sub.2                                                  NH.sub.2     76 R.sub.2          M.sub.2             "   H   3     D.sub.3                             R.sub.2                               M.sub.2                                 SO.sub.3 H                                     H   3'    NH.sub.2                                                  NH.sub.2     77 R.sub.2          M.sub.2             "   H   3     D.sub.3                             R.sub. 2                               M.sub.2                                 H   H   4'    NH.sub.2                                                  NH.sub.2     78 R.sub.2          M.sub.2             "   H   3     D.sub.3                             R.sub.2                               M.sub.2                                 H   H   4'    NH.sub.2                                                  NH.sub.2     79 R.sub.2          M.sub.2             "   H   3     D.sub.3                             R.sub.2                               M.sub.2                                 H   H   4'    NH.sub.2                                                  OH     80 R.sub.2          M.sub.2             "   H   3     D.sub.3                             R.sub.2                               M.sub.2                                 H   H   4'    OH OH     81 R.sub.2          M.sub.2             "   H   4     D.sub.3                             R.sub.2                               M.sub.2                                 H   H   3'    NH.sub.2                                                  NH.sub.2     82 R.sub.3          M.sub.1             H   H   3     D.sub.3                             R.sub.2                               M.sub.2                                 SO.sub.3 H                                     H   4'    NH.sub.2                                                  NH.sub.2     83 R.sub.1          M.sub.4             H   H   3     D.sub.3                             R.sub.2                               M.sub.5                                 "   H   4'    OH NH.sub.2     84 R.sub.4          M.sub.4             H   H   3     D.sub.3                             R.sub.2                               M.sub.6                                 "   H   4'    NH.sub.2                                                  NH.sub.2     85 R.sub.5          M.sub.4             H   H   3     D.sub.3                             R.sub.2                               M.sub.7                                 "   H   4'    NH.sub.2                                                  NH.sub.2     86 R.sub.2          M.sub.2             SO.sub.3 H                 H   4     D.sub.3                             R.sub.2                               M.sub.2                                 H   H   3'    OH NH.sub.2     87 R.sub.2          M.sub.2             "   H   4     D.sub.3                             R.sub.2                               M.sub.2                                 H   H   3'    OH OH     88 R.sub.2          M.sub.8             "   H   4     D.sub.3                             R.sub.2                               M.sub.1                                 H   H   3'    OH OH     89 R.sub.2          M.sub.8             "   H   4     D.sub.3                             R.sub.2                               M.sub.2                                 H   H   3'    OH NH.sub.2     90 R.sub.2          M.sub.8             H   H   4     D.sub.3                             R.sub.2                               M.sub.4                                 SO.sub.3 H                                     H   3'    NH.sub.2                                                  NH.sub.2     91 R.sub.2          M.sub.9             H   H   4     D.sub.3                             R.sub.2                               M.sub.5                                 SO.sub.3 H                                     H   3'    OH NH.sub.2     92 R.sub.2          M.sub.9             H   H   3     D.sub.3                             R.sub.4                               M.sub.3                                 "   H   4'    OH OH     93 R.sub.2          M.sub.8             H   H   3     D.sub.3                             R.sub.5                               M.sub.4                                 "   H   4'    NH.sub.2                                                  NH.sub.2     94 R.sub.2          M.sub.3             H   H   4     D.sub.3                             R.sub.2                               M.sub.3                                 "   H   3'    NH.sub.2                                                  NH.sub.2     95 R.sub.2          M.sub.2             H   CH.sub.3                     3     D.sub.3                             R.sub.2                               M.sub.2                                 "   H   4'    OH OH     96 R.sub.2          M.sub.3             H   Cl  3     D.sub.3                             R.sub.2                               M.sub.3                                 "   H   4'    NH.sub.2                                                  NH.sub.2     97 R.sub.2          M.sub.2             H   OCH.sub.3                     3     D.sub.3                             R.sub.2                               M.sub.4                                 "   H   4'    NH.sub.2                                                  NH.sub.2     98 R.sub.2          M.sub.7             SO.sub.3 H                 H   4     D.sub.3                             R.sub.2                               M.sub.7                                 H   Cl  3'    OH OH     99 R.sub.2          M.sub.8             "   H   4     D.sub.3                             R.sub.2                               M.sub.2                                 H   CH.sub.3                                         3'    OH NH.sub.2     100        R.sub.2          M.sub.6             "   H   4     D.sub.3                             R.sub.2                               M.sub.2                                 H   OCH.sub.3                                         3'    NH.sub.2                                                  NH.sub.2     101        R.sub.2          M.sub.2             "   H   3     D.sub.3                             R.sub.2                               M.sub.2                                 H   H   3'    OH NH.sub.2     102        R.sub.2          M.sub.2             "   H   4     D.sub.3                             R.sub.2                               M.sub.2                                 H   H   4'    NH.sub.2                                                  NH.sub.2     103        R.sub.2          M.sub.2             "   H   4     D.sub.3                             R.sub.2                               M.sub.2                                 SO.sub.3 H                                     H   4'    NH.sub.2                                                  NH.sub.2     104        R.sub.2          M.sub.2             "   H   3     D.sub.3                             R.sub.2                               M.sub.2                                 H   H   3'    NH.sub.2                                                  NH.sub.2     105        R.sub.2          M.sub.2             "   H   4     D.sub.3                             R.sub.2                               M.sub.2                                 H   H   4'    NH.sub.2                                                  OH     106        R.sub.2          M.sub.2             "   H   3     D.sub.3                             R.sub.2                               M.sub.2                                 SO.sub.3 H                                     H   4'    OH NH.sub.2     107        R.sub.2          M.sub.10             "   H   3     D.sub.3                             R.sub.2                               M.sub.2                                 H   H   3'    OH OH     __________________________________________________________________________

EXAMPLE 108

11.5 Parts (0.05 mole) of 1-amino-3-acetylaminobenzene-6-sulphonic acid are diazotised according to known methods with 3.45 parts (0.05 M) sodium nitrite at 0°-5° in the presence of hydrochloric acid and the resulting diazonium salt is then coupled at pH 8-9 with 5.5 parts (0.05 M) of 1,3-dihydroxybenzene. The dyestuff of formula (108 a) ##STR67## is obtained.

7.5 Parts (0.05 M) of 4-aminoacetanilide are diazotised with 3.45 parts (0.05 M) sodium nitrite at 0°-5° and then coupled at pH 9-10.5 with the dyestuff of formula (108 a). The resulting isomer mixture is then hydrolysed at 100° with a solution of 5% sodium hydroxide, to give a mixture of formula (108 b) ##STR68##

21.4 Parts (0.05 M) of the dyestuff mixture of formula (108 b) are tetrazotised with 6.9 parts (0.1 M) of sodium nitrite at 0°-5° in the presence of hydrochloric acid and then coupled at pH 2-3 with 28.7 parts (0.1 M) of 6-hydroxy-4-methyl-1-(3'-dimethylaminopropyl)-3-pyridiniumpyrid-2-one chloride. There is obtained a mixture of dyestuffs of formula (108 c) ##STR69## which dyes paper in a brown shade. The arrows indicate the coupling positions.

By following the procedure described in one of the preceding Examples, the compounds of formula (108 d) ##STR70## in which d₄ is H or D₄ ##STR71## and R_(a), R_(b), R₅, R₆, B₁, B₂, M_(a) and M_(b) have the significances indicated in Table 5 below, may be prepared.

In the formula (108 d), the arrows indicate the coupling positions.

                                      TABLE 5     __________________________________________________________________________                 Position of     Position of     Ex.         the azo  ○3                                 the azo  ○4     Nr.        Ra          Ma R.sub.5                 on ring D                       d.sub.4                         R.sub.b                           M.sub.b                             R.sub.6                                 on ring E                                       B.sub.1                                           B.sub.2     __________________________________________________________________________     109        R.sub.2          M.sub.2             SO.sub.3 H                 1     H --                           --                             --  --    OH  OH     110        R.sub.2          M.sub.2             "   1     H --                           --                             --  --    NH.sub.2                                           NH.sub.2     111        R.sub.2          M.sub.2             "   2     H --                           --                             --  --    OH  NH.sub.2     112        R.sub.2          M.sub.2             "   2     H --                           --                             --  --    NH.sub.2                                           NH.sub.2     113        R.sub.2          M.sub.2             "   1     D.sub.4                         R.sub.2                           M.sub.2                             H   1'    OH  NH.sub.2     114        R.sub.2          M.sub.2             "   1     D.sub.4                         R.sub.2                           M.sub. 2                             H   1'    NH.sub.2                                           NH.sub.2     115        R.sub.2          M.sub.2             "   1     D.sub.4                         R.sub.2                           M.sub.2                             SO.sub.3 H                                 1'    OH  OH     116        R.sub.2          M.sub.2             "   1     D.sub.4                         R.sub.2                           M.sub.2                             H   2'    OH  OH     117        R.sub.2          M.sub.2             "   1     D.sub.4                         R.sub.2                           M.sub.2                             H   2'    NH.sub.2                                           NH.sub.2     118        R.sub.2          M.sub.2             "   1     D.sub.4                         R.sub.2                           M.sub.2                             SO.sub.3 H                                 2'    OH  NH.sub.2     119        R.sub.2          M.sub.2             "   2     D.sub.4                         R.sub.2                           M.sub.2                             "   2'    OH  OH     120        R.sub.3          M.sub.3             "   1     D.sub.4                         R.sub.3                           M.sub.3                             H   1'    OH  OH     121        R.sub.2          M.sub.4             "   1     D.sub.4                         R.sub.2                           M.sub.4                             H   2'    NH.sub.2                                           NH.sub.2     122        R.sub.2          M.sub.5             H   1     D.sub.4                         R.sub.2                           M.sub.5                             SO.sub.3 H                                 2'    NH.sub.2                                           OH     123        R.sub.2          M.sub.6             H   2     D.sub.4                         R.sub.2                           M.sub.6                             "   1'    OH  OH     124        R.sub.3          M.sub.7             H   2     D.sub.4                         R.sub.3                           M.sub.7                             "   1'    NH.sub.2                                           OH     125        R.sub.1          M.sub.8             SO.sub.3 H                 2     D.sub.4                         R.sub.1                           M.sub.8                             "   1'    OH  OH     126        R.sub.1          M.sub.8             "   2     D.sub.4                         R.sub.1                           M.sub.8                             H   1'    NH.sub.2                                           NH.sub.2     127        R.sub.2          M.sub.9             "   1     D.sub.4                         R.sub.2                           M.sub.9                             H   2'    OH  NH.sub.2     128        R.sub.2          M.sub.2             "   2     D.sub.4                         R.sub.2                           M.sub.2                             H   1'    OH  OH     129        R.sub.2          M.sub.2             H   2     D.sub.4                         R.sub.2                           M.sub.2                             SO.sub.3 H                                 1'    OH  OH     130        R.sub.2          M.sub.2             SO.sub.3 H                 2     D.sub.4                         R.sub.2                           M.sub.2                             H   1'    NH.sub.2                                           NH.sub.2     131        R.sub.2          M.sub.2             H   2     D.sub.4                         R.sub.2                           M.sub.2                             SO.sub.3 H                                 1'    NH.sub.2                                           NH.sub.2     132        R.sub.2          M.sub.2             SO.sub.3 H                 2     D.sub.4                         R.sub.2                           M.sub.2                             "   1'    NH.sub.2                                           NH.sub.2     133        R.sub.2          M.sub.2             "   1     D.sub.4                         R.sub.2                           M.sub.2                             "   1'    NH.sub.2                                           NH.sub. 2     134        R.sub.2          M.sub.2             H   2     D.sub.4                         R.sub.2                           M.sub.2                             "   1'    OH  NH.sub.2     135        R.sub.2          M.sub.2             SO.sub.3 H                 2     D.sub.4                         R.sub.2                           M.sub.2                             "   1'    OH  NH.sub.2     136        R.sub.2          M.sub.2             "   1     D.sub.4                         R.sub.2                           M.sub.2                             "   1'    OH  NH.sub.2     __________________________________________________________________________

EXAMPLE 137

(1) 26.1 Parts (0.05 M) of the diazonium salt of the compound of formula (137 a) ##STR72## prepared by diazotation of 1-amino-4-acetylaminobenzene-6-sulphonic acid, coupling with the corresponding pyridone and hydrolysis of the acetyl group according to known methods,

are coupled with 29 parts (0.05 M) of the compound of formula (137 b) ##STR73##

The resulting dyestuff is of formula (137 c) ##STR74##

11.13 Parts (0.01 M) of the compound of formula (137 c) are reacted with 2.5 parts (0.01 M) of copper sulphate (CuSO₄ ·5H₂ O) in water at 70°, at pH 4.0-4.8 to give the corresponding 1:1 copper complex.

(2) 26.1 Parts (0.05 M) of the diazonium salt of the compound of formula (137 a) are coupled with 29 parts (0.05 M) of the compound of formula (137 d) ##STR75## to give the compound of formula (137 e) ##STR76##

The compound of formula (137 d) may be prepared in accordance with known methods:

nitration of 4-acetylamino-1-hydroxybenzene to 4-acetylamino-2-nitro-1-hydroxybenzene

reduction according to Bechamp

diazotation and coupling with the pyridone

hydrolysis of the acetyl group

diazotation and coupling with 1,3-dihydroxybenzene.

(2a-d) 11.13 parts (0.01 M) of the compound of formula (137 e) are converted into metal complexes (Cu, Cr, Co, Fe) according to the procedure disclosed for the compound of formula (137 c).

APPLICATION EXAMPLE A

70 Parts of chemically bleached sulphite cellulose obtained from pinewood and 30 parts of chemically bleached sulphite cellulose obtained from birchwood are ground in 2000 parts of water in a Hollander. 0.2 Parts of the dyestuff of formula (1 b) of Example 1 in salt for are added into this pulp. Paper is produced from this pulp after mixing for 20 minutes. The absorbent paper which is obtained in this manner is dyed in a brown tone and the waste water is practically colourless.

APPLICATION EXAMPLE B

0.5 Parts of the dyestuff of formula (1 b) of Example 1 used in salt form are added to 100 parts of chemically bleached sulphite cellulose which have been ground in a Hollander with 2000 parts of water. Sizing takes place after a thorough mixing for 15 minutes. The paper which is produced from this material has a brown tone and has good wet fastness properties.

APPLICATION EXAMPLE C

An absorbent web of unsized paper is drawn at a temperature of 40° to 50° through a dye solution having the following composition:

0.5 parts of the dyestuff of formula (1 b) of Example 1 in salt form)

0.5 parts of starch

99.0 parts of water.

The excess dye solution is squeezed out through two rollers. The dried web of paper is dyed in a brown tone.

Any one of the dyes of Examples 2 to 137 may be used either in water-soluble salt form or in the form of a dye preparation, e.g. granulates in any one of Application Examples A to C.

APPLICATION EXAMPLE D

100 Parts of freshly tanned and neutralized chrome leather are agitated for 30 minutes in a vessel with a dyebath of 250 parts of water and 1 part of the dyestuff of formula (1 b) of Example 1 (in salt form) at 55° and are then treated in the same bath for 30 minutes with 2 parts of an anionic fatty liquor based on sulphonated train oil. The leather is then dried and prepared in the normal way, giving a leather evenly dyed in a brown tone.

Other low affinity vegetable retanned leathers can be similarly dyed by known methods, using any one of the dyestuffs of Examples 2 to 137.

APPLICATION EXAMPLE E

2 Parts of the dyestuff of Example 1 (in salt form) are dissolved in 4000 parts of demineralised water at 40°. 100 Parts of a prewetted cotton textile substrate are added and the bath is raised to boiling point over 30 minutes and held at the boil for 1 hour, topping up with water where necessary. Upon removal of the dyed fabric from the bath, washing and drying, a brown dyeing is obtained with good light fastness and wet fastness properties. The dyestuff exhausts practically totally and the waste water is practically colourless.

Any one of the dyestuffs of Examples 2 to 137 may be used in place of that of Example 1 in any one of Application Examples D and E.

Application Example F 15 kg waste paper, 25 kg bleached mechanical pulp and 10 kg unbleached sulphate cellulose are defibrated in a pulper into a 3% aqueous pulp slurry. This stock suspension is diluted to 2% in a dyeing chest. To this diluted suspension there are added at first 5% by weight china clay and the 1.25 kg of a 5% acetic acid solution of the dyestuff of formula (1 b) of Example 1, the % being based on the dry weight of fibres. After 20 minutes, a 1% resin size dispersion (based on the weight of absolutely dry fibres) is added to the resulting pulp in the mixing chest. The homogeneous pulp slurry is then adjusted to pH 5 by addition of alum shortly before introduction into the paper machine.

A brown 80 g/m² heavy bag paper is produced on the paper machine. The resulting dyed paper exhibits very good fastness properties to bleeding according to DIN 53 991 and good light fastness properties.

The resulting paper can almost completely be decolourized by hypochlorite.

EXAMPLE G

Water is added to a dry pulp in a hollander consisting of 60% by weight of mechanical wood pulp and 40% by weight of unbleached sulphite cellulose and the slurry is beaten in order to obtain a dry content slightly exceeding 2.5% and having a beating degree of 40 SR. The slurry is then exactly adjusted to a high density dry content of 2.5%.

5 Parts of a 0.25% aqueous solution of the dyestuff of formula (1 b) of Example 1 are added to 200 parts of the above resulting slurry. The mixture is stirred for about 5 minutes and, after addition of 2% by weight resin size and then 4% by weight alum (based on the dry weight) is further stirred for a few minutes until homogeneous. The resulting pulp is diluted with about 500 parts water to a volume of 700 parts and then used for the production of sheets by suction on a sheet former. The resulting paper sheets are dyed in an intense brown shade. The residual dyestuff concentration in the waste water from the sheet former has been measured photometrically and is substantially low.

Any one of the dyestuffs of Examples 2 to 137 may be used in place of that of Example 1 in any one of Application Examples F and G. The waste water exhibits a substantially low residual dyestuff concentration. 

What is claimed is:
 1. A composition of matter which is (i) a metal-free compound of the formula ##STR77## or a salt thereof, (ii) a 1:1 complex of a metallizable compound of Formula I, or a salt thereof, (iii) a 1:2 metal complex of a metallizable compound of Formula I, or a salt thereof, (iv) a 1:2 metal complex of two metallizable compounds of Formula I, or a salt thereof, (v) a 1:2 metal complex of a metallizable compound of Formula I and a metallizable compound not of Formula I, or a salt thereof, or (vi) a mixture thereof, wherein each of B₁ and B₂ is independently hydroxy or amino,each D is independently ##STR78## wherein R is hydrogen, C₁₋₄ alkyl, C₅₋₆ cycloalkyl, phenyl, benzyl or phenylethyl,R₁ is hydrogen, cyano, --COOR₄, --CONR₅ R₆, --SO₂ NR₅ R₆, ##STR79## wherein each R₃ is independently hydrogen, C₁₋₄ alkyl, --NR₅ R₆ or --CONR₅ R₆,R₄ is C₁₋₆ alkyl or phenyl(C₁₋₃ alkyl), R₇ is C₁₋₄ alkyl, R₈ is hydrogen or C₁₋₄ alkyl, and R₉ is --S--, --O-- or --NR₅ --, R₂ is hydrogen, hydroxy or C₁₋₄ alkoxy, R_(2a) is hydrogen, C₁₋₄ alkyl or halo, M is hydrogen; C₁₋₈ alkyl; (C₁₋₄ alkoxy)-C₁₋₄ alkyl; C₂₋₄ hydroxyalkyl; C₅₋₆ cycloalkyl; C₅₋₆ cycloalkyl substituted by 1 to 3 C₁₋₄ alkyl groups; phenyl(C₁₋₃ alkyl); phenyl(C₁₋₃ alkyl) the phenyl group of which is substituted by 1 to 3 C₁₋₄ alkyl groups; --NR₁₁ R₁₂ ; --A₁ --NR₁₃ R₁₄ ; --A₂ --N.sup.⊕ R₁₃ R₁₄ R₁₅ A.sup.⊖ or ##STR80## wherein A₁ is linear or branched C₁₋₆ alkylene or linear or branched C₂₋₆ alkenylene,A₂ is linear or branched C₂₋₆ alkylene or linear or branched C₂₋₆ alkenylene, R₁₀ is linear or branched C₁₋₁₀ alkylene; linear or branched C₂₋₁₀ alkenylene; linear or branched alkylene or alkenylene having a maximum of 10 carbon atoms and interrupted by 1 or 2 atoms selected from oxygen and nitrogen; phenylene; or cyclohexylene, R₁₆ is hydrogen, halo, nitro, C₁₋₄ alkyl or C₁₋₄ alkoxy, R₂₀ is hydrogen, --CO--(CH₂)_(m) --NR₁₁ R₁₂, --CO--(CH₂)_(m) --N.sup.⊕ R₁₃ R₁₄ R₁₅ A.sup.⊖ or ##STR81## wherein m is 1 to 6, with the proviso that R₂₀ is other than hydrogen when q is 0, and q is 0 or 1, v is 0, 1 or 2, and each n is independently 0 or 1,wherein each R₅ and R₆ is independently hydrogen or C₁₋₄ alkyl, or --NR₅ R₆ is morpholino; pyrrolidino; piperidino; piperazino; or morpholino, pyrrolidino, piperidino or piperazino substituted by 1 to 3 C₁₋₄ alkyl groups, each R₁₁ and R₁₂ is independently hydrogen; C₁₋₆ alkyl; C₂₋₆ alkyl monosubstituted by halo, hydroxy or cyano; phenyl(C₁₋₃ alkyl); phenyl(C₁₋₃ alkyl) the phenyl group of which is substituted by 1 to 3 substituents selected from halo, C₁₋₄ alkyl and C₁₋₄ alkoxy; C₅₋₆ cycloalkyl; or C₅₋₆ cycloalkyl substituted by 1 to 3 C₁₋₄ alkyl groups, or --NR₁₁ R₁₂ is morpholino; pyrrolidino; piperidino; piperazino; or morpholino, pyrrolidino, piperidino or piperazino substituted by 1 to 3 C₁₋₄ alkyl groups, each R₁₃ and R₁₄ is independently hydrogen; C₁₋₆ alkyl; C₂₋₆ alkyl monosubstituted by halo, hydroxy or cyano; phenyl(C₁₋₃ alkyl); phenyl(C₁₋₃ alkyl) the phenyl group of which is substituted by 1 to 3 substituents selected from halo, C₁₋₄ alkyl and C₁₋₄ alkoxy; C₅₋₆ cycloalkyl; or C₅₋₆ cycloalkyl substituted by 1 to 3 C₁₋₄ alkyl groups, and each R₁₅ is independently C₁₋₄ alkyl or phenyl(C₁₋₄ alkyl), or --N.sup.⊕ R₁₃ R₁₄ R₁₅ is N-R₁₅ -morpholinium; N-R₁₅ -pyrrolidinium; N-R₁₅ -piperidinium; N-R₁₅ -piperazinium; N-R₁₅ -morpholinium, N-R₁₅ -pyrrolidinium, N-R₁₅ -piperidinium or N-R₁₅ -piperazinium substituted by 1 to 3 C₁₋₄ alkyl groups; pyridinium; pyridinium substituted by 1 to 3 C₁₋₄ alkyl groups; or ##STR82## wherein R₁₅ ' is methyl, ethyl, propyl or benzyl,Wa is --S--, --SO--, --SO₂ --, --NR_(50a) -- or --.sup.⊕ N(R₁₅ ')₂ -- A.sup.⊖, whereinR_(50a) is benzyl or C₁₋₄ alkyl substituted by amino, and R₁₅ ' is as defined above, and R₁₅ is as defined above, R₁₇ is halo, hydroxy, C₁₋₄ alkoxy, phenyl, amino or an aliphatic, cycloaliphatic, aromatic or heterocyclic amino group the nitrogen atom of which is attached to the 1,3,5-triazine ring, and R₁₈ is an aliphatic, cycloaliphatic, aromatic or heterocyclic amino group the nitrogen atom of which is attached to the 1,3,5-triazine ring,wherein each A.sup.⊖ is independently a non-chromophoric anion, and each halo is independently fluoro, chloro, bromo or iodo, with the provisos that (1) when the compound of Formula I is free of sulfo groups, it contains at least one water-solubilizing protonatable basic or cationic group, (2) when the compound of Formula I contains at least one sulfo group, the total number of water-solubilizing basic and cationic groups that it contains exceeds the number of sulfo groups that it contains by at least one, (3) when the composition of matter is a metal-free compound of Formula I, or a salt thereof, at least one n is 1, at least one v is 1, at least one R₂ is hydroxy or C₁₋₄ alkoxy or at least one R_(2a) is halo, and (4) when the composition of matter is a 1:2 metal complex, or a salt thereof, the negative charge of the complexed metal ion is balanced by hydrogen or a non-chromophoric cation.
 2. A composition of matter according to claim 1 which is a metal-free compound, or a salt thereof, a mixture of metal-free compounds or salts or a mixture of metal-free compounds and salts.
 3. A composition of matter according to claim 1 whereinR₁₀ is linear or branched C₁₋₁₀ alkylene, linear or branched C₂₋₁₀ alkenylene, phenylene or cyclohexylene, each R₁₃ is independently R₁₃ ', each R₁₄ is independently R₁₄ ', each R₁₅ is independently R₁₅ ', or --.sup.⊕ NR₁₃ R₁₄ R₁₅ is --N.sup.⊕ R₁₃ 'R₁₄ 'R₁₅ ', R₁₇ is chloro, hydroxy, methoxy, amino, N,N-di-(C₂₋₄ hydroxyalkyl)amino, --NR₅ 'R₁₉, ##STR83## wherein R₁₆ ' is hydrogen, chloro, nitro, methyl or methyoxy, andR₅₁ is hydrogen, C₁₋₄ alkyl or C₁₋₄ alkyl substituted by amino, and R₁₈ is --NR₅ 'R₁₉,wherein each R₁₉ is independently C₁₋₁₂ alkyl; C₁₋₁₂ hydroxyalkyl; alkyl having a maximum of 12 carbon atoms which is interrupted by 1 to 3 radicals selected from --NR₅ -- and --N.sup.⊕ (R₇)₂ -- A.sup.⊖ ; alkyl having a maximum of 12 carbon atoms which is substituted by hydroxy and interrupted by 1 to 3 radicals selected from --NR₅ -- and --N.sup.⊕ (R₇)₂ -- A.sup.⊖ ; --NH--CO--CH₂ --Z₁ ; --CH₂ --CO--NH--Y--Z₁ ; --Y--Z₁ ; ##STR84## wherein R₂₁ is hydrogen, halo, hydroxy, nitro, C₁₋₄ alkyl or C₁₋₄ alkoxy,each Y is independently linear or branched C₁₋₈ alkylene or linear or branched C₃₋₈ alkylene, and Z_(o) is dimethylamino, diethylamino, trimethylammonium A.sup.⊖, triethylammonium A.sup.⊖, --CO--Y_(o) --Z₁, --CO--NH--Y_(o) --Z₁, --SO₂ --NH--Y_(o) --Z₁, --NH--CO--Y_(o) --Z₁, --Y_(o) --Z₁ or --NHNH--CO--CH₂ --Z₁, whereinY_(o) is linear or branched C₁₋₄ alkylene,wherein each R₅ ' is independently hydrogen, methyl or ethyl, each R₇ is independently C₁₋₄ alkyl, and each Z₁ is independently --NR₁₁ 'R₁₂ ' or --N.sup.⊕ R₁₃ 'R₁₄ 'R₁₅ ' A.sup.⊖,wherein each R₁₁ ' and R₁₂ ' is independently hydrogen, C₁₋₆ alkyl, n-C₂₋₃ hydroxyalkyl, benzyl, 2-cyanoethyl or 2-chloroethyl, or --NR₁₁ 'R₁₂ ' is morpholino, pyrrolidino, piperidino, piperazino or N-C₁₋₄ alkylpiperazino, each R₁₃ ' and R₁₄ ' is independently C₁₋₆ alkyl, n-C₂₋₃ hydroxyalkyl, benzyl, 2-cyanoethyl or 2-chloroethyl, each R₁₅ ' is independently methyl, ethyl, propyl or benzyl, or --N.sup.⊕ R₁₃ R₁₄ 'R₁₅ ' is pyridinium, methylpyridinium, dimethylpyridinium or ##STR85## wherein W is a direct bond, --CO₂ --, --O--, --S--, --SO--, --SO₂ --, --NH--, --NR₅₀ -- or --.sup.⊕ N(R₁₅ ')₂ -- A.sup.⊖, whereinR₅₀ is C₁₋₄ alkyl, benzyl or C₁₋₄ alkyl substituted by amino, and R₁₅ ' is as defined above.
 4. A composition of matter according to claim 3 which is a metal-free compound or a salt thereof, a mixture of metal-free compounds or salts or a mixture of metal-free compounds and salts.
 5. A composition of matter according to claim 3 whereinR₁₇ is chloro, hydroxy, methoxy, amino, C₁₋₂ alkylamino, C₂₋₄ hydroxyalkylamino, N,N-di-(C₂₋₄ hydroxyalkyl)amino, --NR₅ "R₁₉ ', ##STR86## and R₁₈ is --NR₅ "R₁₉ ',wherein each R₁₉ ' is independently --(CH₂)_(a) --NR₅ "--CH₃, --(CH₂)_(a) --NR₅ "--C₂ H₅, --(CH₂)_(a) --NR₅ "--(CH₂)_(a) --NR₅ "--C₂ H₅, --(CH₂)_(a) --N.sup.⊕ (R₁₃ ")₂ --C₂ H₅ A.sup.⊖, --(CH₂)_(a) --N.sup.⊕ (R₁₃ ")₂ --(CH₂)_(a) --N.sup.⊕ (R₁₃ ")₂ --C₂ H₅ 2A⁶³, --NH--CO--CH₂ --Z₂, --CH₂ --CO--NH--Y'--Z₂, --Y"--Z₂, ##STR87## wherein each Y' is independently linear or branched C₁₋₄ alkylene,Z_(o) is dimethylamino, trimethylammonium A.sup.⊖, --CO--NH--Y_(o) '--Z₂, --NH--CO--Y_(o) '--Z₂, --CO--Y_(o) '--Z₂, --SO₂ --NH--Y_(o) '--Z₂, --Y_(o) '--Z₂ or --NHNH--CO--CH₂ --Z₂, whereinY_(o) ' is linear or branched C₂₋₄ alkylene, and each a is independently 2 or 3,wherein each R₅ " is independently hydrogen or methyl, each R₇ ' is independently methyl or ethyl, and each Z₂ is independently --NR₁₁ "R₁₂ " or --N.sup.⊕ R₁₃ "R₁₄ "R₁₅ " A.sup.⊖,wherein each R₁₁ " and R₁₂ " is independently hydrogen, methyl or ethyl, or --NR₁₁ "R₁₂ " is morpholino, piperazino or N-methylpiperazino, each R₁₃ " and R₁₄ " is independently methyl or ethyl, and each R₁₅ " is independently methyl, ethyl or benzyl, or --N.sup.⊕ R₁₃ "R₁₄ "R₁₅ " is pyridinium, 2-picolinium, 3-picolinium, N-methylmorpholinium, N-methylpiperidinium, N-methylpiperazinium or N,N'-dimethylpiperazinium.
 6. A composition matter according to claim 5 which is a metal-free compound or a salt thereof, a mixture of metal-free compounds or salts or a mixture of metal-free compounds and salts.
 7. A composition of matter according to claim 3 which is (i) a metal-free compound of the formula ##STR88## or a salt thereof, (ii) a 1:1 metal complex of a metallizable compound of Formula Ia, or a salt thereof, (iii) a 1:2 metal complex of a metallizable compound of Formula Ia, or a salt thereof, (iv) a 1:2 metal complex of two metallizable compounds of Formula Ia, or a salt thereof, (v) a 1:2 metal complex of a metallizable compound of Formula Ia and a metallizable compound not of Formula Ia, or a salt thereof, or (vi) a mixture thereof, whereineach D' is independently ##STR89## wherein R' is methyl, ethyl, phenyl, benzyl or cyclohexyl,R₁ ' is hydrogen, cyano, --CONR₅ 'R₆ ' or ##STR90## wherein each R₃ ' is independently hydrogen, methyl, ethyl, amino or dimethylamino, R₂ ' is hydrogen, hydroxy or methoxy, and M' is hydrogen, methyl, ethyl, 2-hydroxyethyl, 2-methyoxyethyl, 2-ethoxyethyl, cyclohexyl, benzyl, --CH₂ NR₁₃ 'R₁₄ ', --(CH₂)₂ --NR₁₃ 'R₁₄ ', --(CH₂)₃ --NR₁₃ 'R₁₄ ', --(CH₂)₂ --N.sup.⊕ R₁₃ 'R₁₄ 'R₁₅ ' A.sup.⊖, --(CH₂)₃ --N.sup.⊕ R₁₃ 'R₁₄ 'R₁₅ ' A.sup.⊖ or ##STR91## wherein R₁₀ ' is linear or branched C₁₋₈ -alkylene, m-phenylene or p-phenylene,R₁₆ ' is hydrogen, chloro, nitro, methyl or methoxy, and R₂₀ ' is hydrogen, --CO--CH₂ Z₁, --CO--(CH₂)₂ --Z₁ or ##STR92## with the proviso that R₂₀ ' is other than hydrogen when q is 0, wherein each R₅ ' and R₆ ' is independently hydrogen, methyl or ethyl, or --NR₅ 'R₆ ' is morpholino, pyrrolidino, piperidino, piperazino or N-C₁₋₄ alkylpiperazino, R₁₇ ' is chloro, hydroxy, methyoxy, amino, N,N-di-(C₂₋₄ hydroxyalkyl)amino, --NR₅ 'R₁₉, ##STR93## R₁₈ ' is --NR₅ 'R₁₉.
 8. A composition of matter according to claim 7 which is a metal-free compound or a salt thereof, a mixture of metal-free compounds or salts or a mixture of metal-free compounds and salts.
 9. A composition of matter according to claim 7 whereinR₁₇ ' is chloro, hydroxy, methoxy, amino, C₁₋₂ alkylamino, C₂₋₄ hydroxyalkylamino, N,N-di-(C₂₋₄ hydroxyalkyl)amino, --NR₅ "R₁₉ ', ##STR94## R₁₈ ' is --NR₅ "R₁₉ ', wherein each R₁₉ ' is independently --(CH₂)_(a) --NR₅ "--CH₃, --(CH₂)_(a) --NR₅ "--C₂ H₅, --(CH₂)_(a) --NR₅ "--(CH₂)_(a) --NR₅ "--C₂ H₅, --(CH₂)_(a) --N.sup.⊕ (R₁₃ ")₂ --C₂ H₅ A.sup.⊖, --(CH₂)_(a) --N.sup.⊕ (R₁₃ ")₂ --(CH₂)_(a) --N.sup.⊕ (R₁₃ ")₂ --C₂ H₅ 2A.sup.⊖, --NH--CO--CH₂ --Z₂, --CH₂ --CO--NH--Y'--Z₂, --Y'--Z₂, ##STR95## wherein each Y' is independently linear or branched C₁₋₄ alkylene,Z_(o) ' is dimethylamino, trimethylammonium A⁶¹ , --CO--NH--Y_(o) '--Z₂, --NH--CO--Y_(o) '--Z₂, --CO--Y_(o) '--Z₂, --SO₂ --NH--Y_(o) '--Z₂, --Y_(o) '--Z₂ or --NHNH--CO--CH₂ --Z₂, whereinY_(o) ' is linear or branched C₂₋₄ alkylene, and each a is independently 2 or 3,wherein each R₅ " is independently hydrogen or methyl, each R₇ ' is independently methyl or ethyl, and each Z₂ is independently --NR₁₁ "R₁₂ " or --N.sup.⊕ R₁₃ "R₁₄ "R₁₅ " A.sup.⊖,wherein each R₁₁ " and R₁₂ " is independently hydrogen, methyl or ethyl, or --NR₁₁ "R₁₂ " is morpholino, piperazino or N-methylpiperazino, each R₁₃ " and R₁₄ " is independently methyl or ethyl, and each R₁₅ " is independently methyl, ethyl or benzyl, or --N.sup.⊕ R₁₃ "R₁₄ "R₁₅ " is pyridinium, 2-picolinium, 3-picolinium, N-methylmorpholinium, N-methylpiperidinium, N-methylpiperazinium or N,N'-dimethylpiperazinium.
 10. A composition matter according to claim 9 which is a metal-free compound or a salt thereof, a mixture of metal-free compounds or salts or a mixture of metal-free compounds and salts.
 11. A composition of matter according to claim 9 which is (i) a metal-free compound of the formula ##STR96## or a salt thereof, (ii) a 1:1 metal complex of a metallizable compound of Formula Ib, or a salt thereof, (iii) a 1:2 metal complex of a metallizable compound of Formula Ib, or a salt thereof, (iv) a 1:2 metal comples of two metallizable compounds of Formula Ib, or a salt thereof, (v) a 1:2 metal complex of a metallizable compound of Formula Ib and a metallizable compound not of Formula Ib, or a salt thereof or (vi) a mixture thereof, whereineach D" is independently ##STR97## wherein R" is methyl or phenyl,R₁ " is hydrogen, cyano or ##STR98## wherein R₃ " is hydrogen or methyl, and M" is methyl, ethyl, benzyl,--(CH₂)₂ --NR₁₃ "R₁₄ ", --(CH₂)₃ --NR₁₃ "R₁₄ ", --(CH₂)₂ N.sup.⊕ R₁₃ "R₁₄ "R₁₅ " A.sup.⊖ --(CH₂)₃ N.sup.⊕ R₁₃ "R₁₄ "R₁₅ " A.sup.⊖ or ##STR99## wherein R₁₀ " is 1,2-ethylene, 1,3-propylene, m-phenylene or p-phenylene, R₁₆ " is hydrogen, chloro or methyl, and R₂₀ " is hydrogen, --CO--CH₂ --Z₂ or ##STR100## wherein R₁₇ " is chloro, hydroxy, methoxy, amino, C₁₋₂ alkylamino, C₂₋₄ hydroxyalkylamino, N,N-di-(C₂₋₄ hydroxyalkyl)amino, --NR₅ "R₁₉ ', ##STR101## and R₁₈ " is --NR₅ "R₁₉ '.
 12. A composition of matter according to claim 11 which is a metal-free compound or a salt thereof, a mixture of metal-free compounds or salts or a mixture of metal-free compounds and salts.
 13. A composition of matter according to claim 12 which is a salt of the formula or a mixture of salts comprising the salt of the formula ##STR102## or a mixture thereof.
 14. A composition of matter according to claim 13 which is a salt of the formula ##STR103##
 15. A composition of matter according to claim 13 which is a mixture of salts comprising the salt of the formula ##STR104##
 16. A composition of matter according to claim 1 which is a 1:1 metal complex of the formula ##STR105## or a salt thereof, a mixture of such metal complexes or salts or a mixture of such metal complexes and salts, whereineach D₁ is independently ##STR106## wherein Me is copper, chromium, cobalt, nickel or manganese, andthe floating azo radical on Ring A is in the 3-, 4- or 5-position thereof.
 17. A composition of matter according to claim 1 which is a 1:1 metal complex of the formula ##STR107## a salt thereof, a mixture of such metal complexes or salts or a mixture of such metal complexes and salts whereinB₁₀ is --O-- or --NH--, Me is copper, chromium, cobalt, nickel or manganese, the floating oxy radical attached to Ring C is in the 3- or 4-position and is ortho to the floating azo radical attached to said ring, and p is 0, 1 or
 2. 18. A composition of matter according to claim 1 which is a 1:1 metal complex of the formula ##STR108## or a salt thereof, a mixture of such metal complexes or salts or a mixture of such metal complexes and salts, whereinB₁₀ is --O-- or --NH--, each Me is independently copper, chromium, cobalt, nickel or manganese, and the floating oxy radical attached to Ring C is in the 3- or 4-position thereof and is ortho to the floating azo radical attached to said ring.
 19. A composition of matter according to claim 1 which is (i) a 1:2 chromium, cobalt or iron complex of a metallizable compound of Formula I, or a salt thereof, (ii) a 1:2 chromium, cobalt or iron complex of two metallizable compounds of Formula I, or a salt thereof, (iii) a 1:2 chromium, cobalt or iron complex of a metallizable compound of Formula I and a metallizable compound not of Formula I, or a salt thereof or (iv) a mixture thereof. 